Manual Gas Kinetics and Energy Transfer: v.4: A Review of Chemical Literature (Specialist Periodical Reports)

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On the other hand, for reactions that are not problematically hazardous or for those dominated by slow reaction rates rather than being limited by the rate of heat or mass transfer , [15] the advantages granted by microfluidics becomes less apparent or in fact non-existent. Similarly, those reactions that take advantage of bulk forces like gravity and buoyancy such as distillation, centrifugation and phase separation may be better suited to large scale operation than integration with microfluidics [3].

Even when the microfluidic approach to certain processes is advantageous in terms of speed, throughput, and analytical efficiency, if there lies no obvious constraint in existing practices, then few have chosen to adopt microfluidics in lieu of the familiar ease of using conventional techniques [37]. Thus the challenge for microfluidics lies in attaining the recognition from the research and industrial communities that microfluidic techniques are applicable and superior in a greater range of areas than those in which they are currently being used.

Figure 10 : Examples of multiphase microfluidic applications using gas and liquids. Multiphase reactions those between solids, liquids, gases, etc. The high surface-area-to-volume ratios inherent to microfluidic reactions present great potential advantages for multiphase reactions, but complications with the clogging of solid reagents, in particular, has been a concern [38]. While more recent progress has been made in the synthesis of micro and nano particles through droplet-based microfluidics see figure 11 [39] and of materials using non-Newtonian multiphase microfluidic systems [40], solutions for the operation of continuous flow reactions with relatively large solid particles remain difficult i.

While heterogeneous catalysis where the catalysis is of a different phase to the reagents, often a solid remains less complicated in conventional reactors, systems have successfully been designed to immobilize solid catalysts to microchannel walls to perform three-phase hydrogenation reactions [42]. Figure 11 : Images showing the formation of iron oxide nanoparticles through the coalescence of iron chloride solution droplets with ammonium hydroxide droplets under the influence of an electric field applied by electrodes beside the channel.

Image from Frenz et al. The choice of microfluidic chip material dominates its function [43]. While this presents a variety of options to the operator, factors such as cost, complexity of fabrication, and suitability for involved reagents present distinct pros and cons for each type of material.

For organic chemistry applications, chips made from polydimethylsiloxane PDMS , commonly used due to their low cost and ease of prototyping, are not ideal for organic chemistry high-throughput industrial use, as organic solvents can swell of dissolve PDMS [44]. Chips made of glass see figure 12 , poly methylmethacrylate PMMA , cyclic olefin copolymer COC , teflon, or fluorinated ethylene propylene FEP , coupled with the development of lower cost fabrication techniques will likely allow for a greater range of chemical applications on longer timescales [45]. Figure 12 : Illustration showing the fabrication process of glass based microfluidic chips using wet etching and fusion bonding methods.

Image from Lin et al. An obvious limitation of working with individual, or small amounts of microfluidic reactors, is the production volume capability. When only very small amounts of reagents are involved only small amounts of product will consequently be produced. While this can be effectively side-stepped to some degree through the scaling out of microfluidic systems [47] see section 2.

Very similar to the limitations of microfluidics when using solid reagents see section 3. Figure 13 : Scanning electron microscope SEM image of colloidal silica particles synthesized in a microreactor whose walls were passivated with Polytetrafluoroethylene PTFE in order to prevent particle deposition. Image from Khan et al. Due to the numerous benefits of microfluidics discussed above, many stemming from the scale-dependent processes of heat and mass transfer, microreactors have found application in a variety of academic and industrial areas, such as the synthesis of nanomaterials [50], natural products [51], and various small molecule drugs and pharmaceuticals see figure 14 [37], [52].

While microfluidics up to this point have more commonly been used in an academic setting, their industrial use in growing. This section aims to provide an insight into the numerous applications adopted in research and industry that have expanded upon the fundamental advantages of microfluidics in chemistry outlined above. Figure 14 : Microfluidic chip used for the synthesis of G protein-couple receptor-modulating compounds.

Image from Rodrigues et al. As mentioned above, the relatively small length scales and amounts of chemical material involved with microfluidics significantly mitigates the risk surrounding hazardous materials and exothermic reactions. Reactions with these hazardous characteristics are difficult to scale to an industrial level with conventional batch reactors.

With this in mind, a study performed and compared life-cycle assessments of the conversion of m -bromoanisole into m -anisaldehyde a highly exothermic two-step conversion in both continuous microreactors and semi-continuous batch reactors, finding that the m -anisaldehyde yield decreased with reactor size and in fact, the cryogenic systems required by the macro-scale reactors could be dispensed with due to the superior heat-transfer characteristics of the microreactors [53].

By similar reasoning, microfluidics have been found to be extremely useful in the synthesis of radiochemicals. Radiotracers for positron emission tomography PET exhibit short half-lives, and thus high radioactivity, meaning they must be synthesized rapidly, and in a shielded environment in order to maintain activity for diagnostic use [37].

Microreactors, with their fast and easily contained reactions, have consequently become very effective at the synthesis of PET tracers see figure 15 [54], [55]. In addition to performing reactions that are difficult to perform with conventional means, another element driving wider scale industrial use of microfluidics is their development to be used for reactions that would otherwise be impossible. Such was the case in the development of microreactors for the selective fluorination and perfluoronation of organic compounds [56].

Due to their rapid response times to programmed changes in the microfluidic environment, microreactors are ideal for performing reaction optimizations. Figure 16 : a microfluidic reactor used for reaction optimization where reaction temperature, reagent concentration and residence time were varied to determine optimum reaction conditions for glycosylation reactions. Image from Ratner et al. The continuing growth in commercially available microfluidic devices [58] has helped bridge the gap between academic research and industrial application in relevant fields. The commercial availability of microfluidic devices allows researchers to access this powerful technology without the technical skills and experience needed to fabricate the devices themselves.

Furthermore, any chemical processes that are developed with microfluidics in an academic setting can easily be scaled out, as mentioned above, for industrial use simply by virtue of the fact that the same commercially available microfluidic platforms can be used in both settings [3]. The extended capabilities of microreactors when compared to traditional laboratory techniques also helps narrow the gap between research and industry.

For example, multiphase homogeneously catalysed reactions are usually studied at relatively low temperatures and pressures in order to facilitate the ease of these processes in a small setting, whereas similar techniques in industry are performed at high temperatures and pressures in order to make these processes more economical [59]. Microreactors present the capability of working at similarly high temperatures and pressures to those used in industry, but at a small scale that would otherwise be difficult to achieve in a laboratory setting [60]. The more recent development of droplet-based microfluidics has significantly influenced chemical synthesis, micro and nano fabrication, and synthetic biology [61].

This alternative method of microfluidic processes involves splitting a fluid stream into small, discrete droplets, and provides the added benefits of removing the effects of Taylor dispersion and the subsequently increased ease of droplet transport see figure 17 [62]. Reactions performed in droplets have been shown to have significantly affected reaction kinetics, showing increased equilibrium and forward rate constants as the droplet radius decreased [63].

Droplet-based techniques, by isolating reactions from the microfluidic channel walls, can also prevent microfluidic channel fouling, a problem that can sometimes occur in continuous flow methods [64]. Figure 17 : Schematic of microfluidic droplet generation methods. Common hydrodynamic formation methods are top to bottom T-junction, flow-focusing, and co-flow setups.

Common externally driven methods involve top to bottom involve the use of electromagnetic valves and pneumatic micropumps. Image from Mashaghi et al. Organic photochemistry presents the potential for more sustainable chemical synthesis processes. By achieving selective transformations with high chemical and quantum yields [65], and in many cases requiring no chemical catalysts or activating groups [66], organic photochemistry effectively addresses the principles if green chemistry [67]. Current technologies, however, most often involve energy-demanding mercury lamps, and batch reactors, with difficulty in coupling parameters such as hydrodynamics, radiative transfer, mass transfer, and photochemical kinetics present many process limitations with these methods [65].

Continuous flow microreactor technology, on the other hand, in addition to the advantages offered for chemical processes in general, introduce further benefits to photochemistry, including more precise and efficient control of irradiation time and more effective light penetration [68], [69]. Microfluidics has made significant developments since its emergence in the early s, and has come a long way toward fulfilling early predictions made about its potential. Owing to its operation on the micro-scale, microfluidics presents high surface-area-to-volume ratios to allow for rapid heat and mass transfer and make them ideal for efficient and safe chemical reactions that can be precisely controlled and monitored.

The adoption of microfluidics for chemistry-based purposes i. Indeed, the potential for microfluidics in chemistry has been widely demonstrated in research settings and have seen increased use in industrial settings thanks to the ease with which microreactors can be scaled out, especially as off-the-shelf microfluidic tools become more and more accessible and sophisticated. They have been shown to be particularly useful for hazardous chemical reactions that can become difficult or impossible at larger scales, but beyond that have shown that most chemical reactions can be performed with increased efficiency using microfluidics.

More recent advances in chemical microfluidics have focused primarily on droplet-based techniques, creating the possibility of generating highly monodisperse droplets on chips, merging and breaking them, manipulating their geometry, chemical contents, and internal flow profiles, all with in situ monitoring [61].

These techniques are becoming ever more complex, with demonstrations of double or triple emulsion microstructures being formed by forcing droplets into larger droplets see figure 19 [72]. The obvious next step is to transform these primarily proof-of-concept demonstrations into further productive applications.

Figure 19 : Optical micrograph images of a range of highly monodisperse triple emulsions featuring a controlled number of inner and middle droplets, generated with an extended capillary microfluidic device. Image from Chu et al. Although there is still work to be done before microfluidics may become a more universal feature in laboratories and industrial centers, the primary barrier it faces may in fact be that the benefits it provides to some chemical processes, though very real and accepted, are not pronounced enough to warrant the overhaul of conventional methods and practices.

Perhaps through a combination of further development of these microfluidic tools and wider recognition of their potential as they are used more and more, microfluidics in chemistry will be commonplace and change the way that research and industry are performed. Rodrigues, P. Schneider, and G. Chemie — Int. Elvira, X. Wootton, and A. You, C. Hansen, F. Arnold, and S. Ramsey and J. Johnson, C. Li, B. Rasnow, P. Grandsard, H. Xing, and A. Yin and D. Hansen, E. Skordalakes, J. Berger, and S. Duncanson, T. Lin, A. Abate, S.

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Cook, Timothy Daniel Expanding M cyclam chemistry; cobalt acetylide complexes for charge delocalization, and functionalized nickel complexes for CO2 reduction. Corkran, Sydney Cooper Comparison of processing parameters in large and small scale beef processing plants and their impact on Escherichia coli prevalence.

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Ehlers, Shawn Gregory Rearward visibility issues related to agricultural machinery: Contributing factors, potential solutions. Engerer, Jeffrey D Rapid transient cooling utilizing flash boiling and desorption on graphitic foams. Erdei, Ronald An examination of the employment of the pair programming methodology as a collaborative instructional scaffold on college student procedural learning and programming self-beliefs.

Escalante, Lucio Navarro Discovery and functional analyses of Hessian fly effector-encoding genes. Eun, Joonyup Models and optimization for elective surgery scheduling under uncertainty considering patient health condition. Ewetz, Rickard F Synthesis of clock trees with useful skew based on sparse-graph algorithms.

Faheem Ibeacon based proximity and indoor localization system. Fahmi, Tazin Stress and immunological evaluations of sea urchin treated with four different nutraceuticals. Falk, Courtney Knowledge modeling of phishing emails. Fang, Maureen M Integrating precision machining process capability data into product feature design process. Fan, Jingxian Taming tail latency for erasure-coded, distributed storage systems. Fan, Xiaozhe An LED-based image sensor with energy harvesting and projection capabilities college of technology. Feng, Chao Biophysical studies of the allosteric regulatory mechanism of Syk tandem SH2 domains interacting with immunoreceptor tyrosine-based activation motifs.

Feng, Qingyu Hydrologic and water quality impacts from perennial crop production on marginal lands. Ferialdy, Arfinandi Graph theoretical analysis of the Dynamic Lines of Collaboration model for disruption response. Fezi, Kyle S Modeling transport phenomena and uncertainty quantification in solidification processes. Frappier, Ann M An investigation of composite failure analyses and damage evolution in finite element models.

Fu, Jiahong Uncertainty quantification on industrial high pressure die casting process. Fu, Rong Early parental loss, socioeconomic stressors, and health in later life: Evidence for gender disparity. Gabet, Ryan M A comparative forensic analysis of privacy enhanced web browsers. Gaeta, Christopher M Quit playing with your watch: Perceptions of smartwatch use. Gaffar, Md Explicit and unconditionally stable finite difference time domain methods for general electromagnetic analysis.

Gaitonde, Aalok Jaisheela Uday Thermal transport in lithium ion batteries: An experimental investigation of interfaces and granular materials. Gall, Aaron R Magnesium regulates transcription of the mgtA magnesium transporter gene in Salmonella enterica serovar typhimurium via prolyl-bond formation during translation of the mgtL leader ORF. Ganatra, Yash Yogesh Passive thermal management using phase change materials. Gangaraju, SricharanLochan Machine-to-machine communication for automatic retrieval of scientific data. Ganguly, Samiran Spintronic device modeling and evaluation using modular approach to spintronics.

Gao, Jiejun Nanoparticle toxicity and molecular mechanisms in fish: A case study with silver nanoparticles. Gao, Mengqi Toner usage prediction. Gardner, Nathan W Investigation of an energetic coupling between ligand binding and protein folding. Garrity, Jordan M Design and analysis of a high performance valve. Geesey, Bryce A Utilizing tunable signal interference control topologies with electromechanical resonators. Ge, Jiaqi Sequential pattern mining with uncertain data. Gentry, Patrick L A new reality: Funding formula changes and property tax caps and their effects on the role of the school superintendent in the state of Indiana.

Gettings, Patricia E Understanding the communicative processes of baby boomer women adjusting to retirement: Connecting micro and macro discourses. Ge, Yifan Investigating spatial distribution and dynamics of membrane proteins in polymer-tethered lipid bilayer systems using single molecule-sensitive imaging techniques.

Ghahari, Seyedali The effect of ZnO nanoparticles on thermoelectric behavior and fresh properties of cement paste. Ghosh, Arnab Jyoti Analytical investigation of fretting wear with special emphasis on stress based models. Gilland, Kaitlyn Elizabeth Short-term effects of a Western diet on the number of brainderived neurotrophic factor immunoreactive neurons in the hypothalamic arcuate, ventromedial and paraventricular nuclei.

Glas, Zoe Elizabeth Mitigating conflict: A human dimensions analysis of mesopredators and their management. Glavin, Nicholas Robert Ultra-thin boron nitride films by pulsed laser deposition: Plasma diagnostics, synthesis, and device transport. Goblet, Valentine Pascale Phase of flight identification in general aviation operations.

Lucian Soca. Gokhale, Vaibhav V Design of a helmet with an advanced layered composite for energy dissipation using a multi-material compliant mechanism synthesis. Gomes, Joan Implementation of i-vector algorithm in speech emotion recognition by using two different classifiers: Gaussian mixture model and support vector machine. Goodcase, Eric T The role of attachment insecurity in preferred communication modality and relationship satisfaction of romantic relationships initiated online.

Gradzewicz, Audrey D How small the apocalypse. Green, Colleen Warwick Bad girls in corsets: Women and the transgressive body in the nineteenth century. Greene, Frederick V The path towards clear and convincing digital privacy rights. Griffin-Oliver, Courtney Janai Set and element-level compatibility of spatial and location-word stimuli paired to eye-movement, vocal, and keypress response modalities.


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Groen, Jessica A We'll find the time: Performing traumatic hope through fictions of child maltreatment. Guidry, Brett W Finding the ghost with the machine: Breaking through the assessment center validity ceiling by exploring decisional processes using new sources of behavioral data within virtual assessments. Guo, Tian Effect of bioenergy crops and fast growing trees on hydrology and water quality in the Little Vermilion River Watershed.

Guo, Tianqi The effect of confinement on the development of an axisymmetric wall jet in confined jet impingement. Guo, Xingye Thermomechanical properties of novel lanthanum zirconate based thermal barrier coatings - an integrated experimental and modeling study. Gupta, Ravi Digital signal processors as HPC accelerator and performance tuning via static analysis and machine learning.

Gupta, Rohinish Modelling and control of a parallel through-the-road plug-in hybrid vehicle. Gurule, Kaitlyn An analysis of digital forensic units. Guzzetti, Davide Coupled orbit-attitude mission design in the circular restricted three-body problem. Haderlie, Jacob C Modeling methods for merging computational and experimental aerodynamic pressure data.

Halimi, Ghulam Hazrat Can Afghanistan achieve self-sufficiency in wheat? Limitations due to market integration. Halimi, Ghulam Hazrat Trade and agriculture policy options to improve the wheat subsector in Afghanistan. Hall, Derrick R. Hammond, Max A The influence of collagen crosslinking and treadmill exercise on the mechanics, composition, and morphology of bone at multiple length scales. Han, Arum How training set and prior knowledge affect preschoolers' perception of quantity and early number learning. Han, Chang Wan Characterization of heterogeneous catalysts using advanced transmission electron microscopy techniques.

Haney, Alison M A matter of faith: The role of religion, doubt, and personality in emerging adult mental health. Han, Jaemin Multi-session Network Coding characterization using new linear coding frameworks. Haria, Hiral Jayantilal A novel mode-switching hydraulic hybrid for an on-highway vehicle: A study of architecture and control.

Harris, Mary Beth Women writers and the genealogy of the gentleman: masculinity, authority, and male characters in eighteenth-century English novels by women. Hassan, Khaled MD. Hawkins, Elizabeth Marie Organizing historical agricultural data and identifying data integrity zones to assess agricultural data quality. Hay, Martha E Design of nitroxide-based radical polymer materials for electronic applications. Hayrapetian, Allenoush Analyzing and evaluating security features in software requirements. Hazlitt, Robert A Synthesis of a malvidinglucoside derivative with a difluoromethylene linkage.

Heijnen, Michel J. H Failures in adaptive locomotion in healthy young adults. Heneghan, Joseph M The biology and management of waterhemp in Indiana. Hengge, Neal N Enzymatic liquefaction of untreated corn stover. Herrera Perez, Ruth Marisol Influence of the 3D microenvironment on glioblastoma migration and drug response. He, Zijian Service-level based response by assignment and order processing for warehouse automation. Hickle, Mark D Synthesis, design, and fabrication techniques for reconfigurable microwave and millimeter-wave filters.

Hinh, Robert Tool comparison of semantic parsers. Hinkel, Irina A What is contemporary art? Hjortland, Nicole M Defining the regulatory determinants in substrate catalysis by biochemical, biophysical, and kinetic studies for the development of specific small-molecule inhibitors of ubiquitin specific proteases 7 and Hodde, Whitney The effect of climate change on the economics of conservation tillage: A study based on field experiments in Indiana.

Hodson, Stephen L Carbon nanotube thermal interfaces and related applications. Hoggatt, Will Development of a fluidic mixing nozzle for 3D bioprinting. Holgate, Horane A Development and initial validation of a culturally responsive classroom climate scale. Hollandbeck, Gaelle Florence Effect of volunteer corn density on deoxynivalenol production by Fusarium graminearum in hybrid corn. Hollingshead, Nicole A Examining the influence of Hispanic ethnicity and ethnic bias on medical students' pain decisions.

Holzer, Corey T The application of natural language processing to open source intelligence for ontology development in the advanced persistent threat domain. Hoogewind, Kimberly A Climate change and hazardous convective weather in the United States: Insights from high-resolution dynamical downscaling. Houston, Saori M A longitudinal study of the development of fluency of novice Japanese learners: Analysis using objective measures.

Houtman, John A Design and plan of a modified hydroponic shipping container for research. Hou, Yangyang Low rank methods for optimizing clustering. Hrycik, Allison R Spatio-temporal diet variation and movement decisions of Lake Erie yellow perch. Huang, Hsin-Ying Examination and utilization of rare features in text classification of injury narratives. Huang, Shouyuan Parametric and design analysis on thermoelectric generators.

Huang, Wanfeng Concurrent detection and isolation of cellular and molecular biomarkers. Huang, Wenhan Parallelized ray casting volume rendering and 3D segmentation with combinatorial map. Huang, Yuqian Pattern exploration and event detection from geo-tagged tweets. Huang, Zhi Vehicle sensor-based pedestrian position identification in V2V environment.

Huang, Zun Wave propagation and imaging in structured optical media. Huckabee, Alexis G In-column polymer modifications: Advancing polymer bonded phases. Hudspeth, Matthew C Multi-axial failure of high-performance fiber during transverse impact. Hughes, Kyle M Gravity-assist trajectories to Venus, Mars, and the ice giants: Mission design with human and robotic applications. Hurt, Moriah J Evaluating the physical welfare of dogs in commercial breeding facilities in the United States.

Hussein, Ahmed Mohamed Abd-elhaffiez Effective memory management for mobile environments. Hu, Yaowu Laser shock imprinting of metallic nanostructures and shock processing of low-dimensional materials. Huynh, William B Gesture based non-obstacle interaction on mobile computing devices for dirty working environment. Ibrahim, Md Phyllanthus niruri supplemented diet as a modulator of stress and immune responses in Nile tilapia, Oreochromis niloticus, reared in inland recirculating and aquaponics systems.

Irven, Donovan Being and literature: The disclosure of place in modernity. Issa, Salah F Exploring the cause of injury or death in grain entrapment, engulfment and extrication. Jacobs, Elin M Spatiotemporal patterns of hydroclimatic drivers and soil-water storage: Observations and modeling across scales. Jacobs, Nicholas L Analysis of feedback control applied with command shaping to minimize residual vibration. Jahan, Mafruha Options to improve energy efficiency for educational building. Jahan, Suchana Akter Optimization of conformal cooling channels in 3D printed plastic injection molds.

James Stephen, Julian Securing cloud-based data analytics: A practical approach. Jarmusch, Alan Keith Ambient ionization - mass spectrometry: Advances toward intrasurgical cancer detection. Jauregui, Luis A Electronic transport in nano-devices based on graphene and topological insulators. Javagal, Suhas Raveesh User-centric workload analytics: Towards better cluster management. Jeon, Bonggil A method for selecting HVAC retrofit solutions for existing small- and medium-sized commercial buildings.

Jeong, Jun Young Analysis of structural and functional brain networks. Jiang, Zhengping Multi-scale simulations for high efficiency low power nanoelectronic devices. Jiao, Peng Dynamic green split optimization in intersection signal design for urban street network. Jin, Jonghoon Fast and robust convolutional neural networks optimized for embedded platforms.

Jin, Zhenong Crop modeling for assessing and mitigating the impacts of extreme climatic events on the US agriculture system. Ji, Yanzhu Transposable element and host dynamics in mammals and birds as revealed by transcriptomic and genomic evidence. Johnson, Scott C Observability and observer design for switched linear systems. Jones, Gavin Robert Accessible surface area of common silica particle types.

Jones, Kyle E Hip hop, circulation, and the associational life of Peruvian youth. Jung, Wonyeong Computational investigation of force generation, relaxation, and remodeling of the actin cytoskeleton. Kaczay, Kaitlin R A comparison of the efficacy of radiant and immersion frying using hash brown patties as a model food matrix. Kadasala, Naveen Reddy Synthesis, characterization, and application of magnetic gold nanoclusters. Kalyanam, Rajesh Interactive logical analysis of planning domains.

Kambatla, Karthik Shashank Methods to improve applicability and efficiency of distributed data-centric compute frameworks. Kanani, Geoffrey H An examination of how specific support structures impact the adjustment process of sub-Saharan African students in two Midwestern institutions of higher education. Utilitarian Situations.

Kang, Jisun Improving a mesh segmentation algorithm based on non-negative matrix factorization. Kang, Ji Yun Help-seeking intention among college students: Cross-cultural study between East Asian international students and domestic students in the Unites States. Karki, Anju Investigating the role of the basic helix-loop-helix transcription factor MIST1 in pancreatic diseases.

Karyadi, Kenny A The effects of alcohol odor cues on food and alcohol attentional bias, cravings, and consumption. Kaseb, Ahmed S A cost-effective cloud-based system for analyzing big real-time visual data from thousands of network cameras. Katzman, Tanya Lynn The use of stable isotopes and particulate matter in the investigation of local and regional atmospheric chemistry. Kebede, Ammanuiel A Asphalt pavement preservation using rejuvenating fog seals.

Keith, Melissa G Autonomy and motivation: The impact of task difficulty. Keller, Christine E. M Biochemical changes in animal models of fetal alcohol spectrum disorder. Kendall, Jordan D Hydrocode modeling of oblique impacts into terrestrial planets.

Kesari, Aditi Factors affecting transduction efficiency of pseudotyped viral vectors incorporating alphaviral glycoproteins. Khan, Ishita K Protein function, diversity and functional interplay. Khan, MD Mursalin Assessment of the role of elderberry extract in Nile tilapia, Oreochromis niloticus, as a stress reducing and immune stimulating nutraceutical in-vitro and in-vivo. Khan, M. Ryyan Perspectives and designs towards solar cell performance limits.

Khan, Munib Ahmad Defenders of patrimony a short story collection. Khan, Raza A A high-performance communication topology for decentralized protocols. Kharangate, Chirag Rajan Experimental, theoretical and computational modeling of flow boiling, flow condensation and evaporating falling films. Khatri, Hari Raj Synthetic studies of heparan derivatives: Glycosyl couplings and post-glycosylative modifications. Khern-am-nuai, Warut Essays on value creation in online marketplaces.

Kiernicki, John J Redox-active ligand uranium complexes for approaches to multi-electron chemistry. Kim, Dae Woo New marked point process models for microscopy images. Kim, Huisung Investigation of multimodal forward scatter phenotyping from bacterial colonies. Kim, Hyung Suk Implementing a wireless monitoring solution for a biomechanical telemetry system. Kim, Janghyun Evaluating the performance of passive chilled beams with respect to energy efficiency and thermal comfort.

Kim, Jeonghwan High extinction ratio subwavelength 1D infrared polarizer by nanoimprint lithography. Kim, Jongbum Plasmonic devices based on transparent conducting oxides for near infrared applications.

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Kim, Jooho Examining consumers' risky food consumption behavior in restaurants. Kimmey, David L Feature extraction to improve nowcasting using social media event detection on cloud computing and sentiment analysis. Kim, Min Jung Restaurant menu design and food choice process. Kim, Nicholas Nakjoo Optimal design of sound absorbing systems with microperforated panels. Kirby, Adam Michael Comparing policy decisions for active shooters using simulation modeling. Kissick, Ashley Lorraine Functional diversity enhances detection of ecosystem stability and resolution of predator-prey interactions within a multitrophic community.

Kittell, David E Analysis and simulation of small scale microwave interferometer experiments on non-ideal explosives. Kloster, Kyle Graph diffusions and matrix functions: Fast algorithms and localization results. Koirala, Damodar Mass spectrometric characterization of remotely charged amino acids and peptides. Komanduru, Abi Remote sensing of snow using bistatic radar reflectometry. Kong, Xiangjia An exploratory study of Chinese leave-taking. Konopa, Daniel J Thermal and optical characterization of high power laser diodes. Konstantzos, Iason A human-centered approach for the design of perimeter office spaces based on visual environment criteria.

Kranz, William D Advances in solid phase microextraction for the analysis of volatile compounds in explosives, tire treatments, and entomological specimens. Krishnan, Ankita The broader autism phenotype: Associations with acculturative stress among Asian international students. Kuhlenhoelter, Alisha M Acute impact of a single session of thermotherapy on the expression of angiogenic regulators in human skeletal muscle. Kulakhmetov, Marat F Upscaling ab-initio chemistry models to non-equilibrium flow simulations. Kulczar, Chris The development of preclinical strategies for facilitation of lead candidate selection.

Kulzick, Robert J State based financial liberalization. Kumaravel, Harish Valayapalayam An anomaly-based intrusion detection system based on artificial immune system AIS techniques. Kumavat, Apeksha Dipak Video annotation by crowd workers with privacy-preserving local disclosure. Kustas, Andrew Benjamin Shear-based deformation processing and characterization of electrical steel sheet. Kuykendall, Davis White Leibniz on intra-substantial causation and change. Kwon, Soon Ho Improvement of a biomechanical telemetry system hardware platform. LaFollette, Megan Renee The impact of tickling rats on human-animal interactions and rat welfare.

La Fond, Timothy Controlling for confounding network properties in hypothesis testing and anomaly detection. Larrick, Brienna M 1,Dihydroxyvitamin D regulation of triacylglycerol accumulation in differentiated adipocytes. Larsen, Vance J Responsible microfinance bundling: Experimental evidence on separating insurance and credit offers. Laughery, Lucas Response of high-strength steel reinforced concrete structures to simulated earthquakes. Lavoie, Tegan N Identification and quantification of greenhouse gas emissions from oil and natural gas operations using an aircraft-based mass balance technique.

Lawrence, Katie N Tuning optoelectronic properties of small semiconductor nanocrystals through surface ligand chemistry. Layfield, Allison S Pedagogy and profit: Multiethnic literature, gender and young adult publishing. Lear, Trevor R Liquid metal particle popping: Nanoscale to macroscale. Lee, Alli Elizabeth Exploration of alumni perceptions regarding career development and impact of the Indiana 4-H program. Lee, Heui Chang Device design factors for enhancing the functionality of chronic intracortical microelectrodes. Lee, Jinyoung Investigation of lead exposure as a developmental origin of adult neurodegenerative disease using the zebrafish model system.

Lee, Sangjin Information inference for cyber-physical systems with application to aviation safety and space situational awareness. Lee, Seung Seob Development of new radiation sensors for personal dosimetry. Lee, Woochan Fast time- and frequency-domain finite-element methods for electromagnetic analysis. Lee, Yeunjae Authentic enterprise, communal employee relationship, and employee-generated managerial assets. Legg, Emily M Listening to our stories in dusty boxes: Indigenous storytelling methodology, archival practice, and the Cherokee Female Seminary. Lei, Weiran Enhancing travel experience with the combination of information visualization, situation awareness, and distributed cognition.

Leng, Yujun Preliminary design tools in turbomachinery: Non-uniformly spaced blade rows, multistage interaction, unsteady radial waves, and propeller horizontal-axis turbine optimization. Levine, Stephen E Dynamic transverse debondong of a single s-2 fiber. Li, Ang Flammability limits of alternative aviation fuels. Li, Gaojin Hydrodynamics of swimming microorganisms in complex fluids.

Li, Lingnan Maximum empirical likelihood estimation in U-statistics based general estimating equations. Lili, Wang Climate change impacts on soil erosion and nutrient losses in the Great Lakes region. Lim, Heejong Essays in operations management. Li, Mozhu Differences in context: Revealing expert-novice graph knowledge in biology. Lippitt, Katelyn A Neural processes mediating rhyme processing in young children who stutter.

Lischke, Fabian Design of self-supported 3D printed parts for fused deposition modeling. Liu, Chao Three dimensional moving pictures with a single imager and microfluidic lens. Liu, Chenyang Improving programmability and performance for scientific applications. Liu, Hui Modeling of frame structures undergoing large deformations and large rotations. Liu, Jiabao Numerical optimization of a 6-cylinder diesel engine intake and exhaust manifold. Liu, Shaoqing Quantifying terrestrial ecosystem carbon dynamics with mechanistically-based biogeochemistry models and in situ and remotely sensed data.

Liu, Xiaohui Analysis of a next generation energy system based on the integration of transportation subsystem details. Liu, Xin Water absorption and desorption in concrete. Liu, Xin Analysis of slender structures using mechanics of structure genome and open source codes. Liu, Yangfan Efficient modeling of sound source radiation in free-space and room environments.

Liu, Yu Modifications to Johanson's roll compaction model for improved relative density predictions. Liu, Yucheng Modeling of human perception for near-threshold local distortion in natural images. Liu, Yue Structural studies on cell entry of respiratory enteroviruses. Liu, Yuhang Measuring the effect of cold storage, captive supply, and concentration on the marketing margin in the U. Liu, Yun Three dimensional unsteady flow and active morphing effect in flapping wings. Li, Yiran The effect of static and dynamic aging on fatigue behavior of Sn3.

Li, Yue Hua qian zhao zui shou looking for trouble at own expense - a study of tourist mis behaviors. Li, Zhang Optimal monitoring and mitigation of systemic risk in lending networks. Llanos Lucas, Fernando The role of experience in processing foreign-accented speech. Lockman, Jennifer Danielle College students' suicidal ideation: Testing the predictions of the existential - constructivist theory of suicide.

Lopez Otero, Julio Cesar Bilingualism effects at the syntax-semantic interface: Evidence from the Spanish present tense. Lopez Perez, Nelyan Degradation of high performance polymeric fibers: Effects of sonication, humidity and temperature on poly p-phenylene terephthalamide fibers. Lotz, David Allen Energy dashboard for real-time evaluation of a heat pump assisted solar thermal system. Lou, Fangyuan A study on flow development in an APU-style inlet and its effect on centrifugal compressor performance. Love, Heather A Suicidal ideation following the termination of romantic relationships with consideration of family-of-origin functioning and self-efficacy.

Luan, Chi-Cheng Feelings of doing good for myself or others: Discussing effects of self-conscious emotions on sustainable consumption. Lucas, Jason M Connecting models of configuration spaces: From double loops to strings. Lu, Cheng Content-based image analysis with applications to the multifunction printer imaging pipeline and image databases.

Lui, Pan Priscilla Disentangling universal and cultural-specific risks to mental health among Asian Americans: A multi-site longitudinal investigation. Regulation in Infant Formula Safety. Luo, Qianwen The cloud-radiative forcing of the U. Luo, Zhe Understanding in-plane thermal transport in crystalline semiconducting thin films. Luttermoser, Timothy J Nestmate recognition in odorous house ants Tapinoma sessile : Effects of social plasticity, urbanization, and laboratory maintenance. Lu, Xueting Improving fuel economy during high load diesel engine system operation through valve train flexibility.

Lyle, LaDawn Tiffany A molecular analysis of blood-tumor barrier permeability in three experimental models of brain metastasis from breast cancer. Lyu, Hao Lyu Fight deck human-automation mode confusion detection using a generalized fuzzy hidden Markov model. Macke, Gabriel A Evaluation of a cool-season grass-white clover mixture for low-nitrogen input lawns. Maesschalck, Cis Guy M. De Design, analysis, optimization and control of rotor tip flows. Mahdavi, Arash A system-of-systems approach to ex-ante analysis of profit potential of a project portfolio.

Maier Acosta, Ana Margarita A multiculturalist and sociotransformative approach to entrepreneurship education in Honduras. Ma, Jing Improving online food safety communication: The role of media. Mallett, Lauren B Rootwire. Manish, Raja Profile fitting in crowded astronomical images. Mankani, Bharat R Advances in Raman hyperspectral compressive detection instrumentation for fast label free classification, quantitation and imaging. Man, Mengren Nanophotonics for dark materials, filters, and optical magnetism.

Marathe, Monica Implementation of reliability aware scheduling in an open source scheduling system. Marbouti, Farshid A standards-based grading model to predict students' success in a first-year engineering course. Marcum, Christopher Louis Fundamental studies of collision-activated dissociation CAD of deprotonated model compounds relevant to lignin degradation products. Mares, Jesus O. Marquet, Bryan David Design of an asymmetric reluctance machine for a generator application. Marquez Alcala, German A The labor market consequences of endogenous low-skill migration with a market-based immigration policy.

Martin, Audrey E Biochemical studies on mycobacterial proteins involved in the transport of fatty acids. Marziale, Matthew D Thermal neutron analysis for improvised explosive device detection. Masters, Christine L Encounters beyond the interface: Data structures, material feminisms, and composition. Matin, Saima A Economic viability of flexible biogas pumps in Bangladesh. Mayar, Khalilullah Modernizing the current Afghan engineering education system: Challenges and opportunities. Mayes, Amanda Sue Struggling students become successful art mentors: A mixed methods multi-case study.

Ma, Yue Amplifying the connection between empty nest parents and their children through ambient information design. Mazzurco, Andrea Methods to facilitate community participation in humanitarian engineering projects: Laying the foundation for a learning platform. McDermott, Keith A A mixed methods study: Evaluating the relationship of project manager competencies and it project management methodologies.

McKenna, Lindsay N Vocalizations of sea turtle hatchlings and embryos. McMasters, James F Development and characterization of targeted poly NIPAm nanoparticles for delivery of anti-inflammatory peptides in peripheral artery disease and osteoarthritis. McMillan, John Ernest Annual forage cropping-systems for midwestern ruminant livestock production.

Mei, Henry Coupled resonator based wireless power transfer for bioelectronics. Mejia, Jessica Animals and the value of life. Mendoza Garcia, John A A phenomenographic study of the ability to address complex socio-technical systems via variation theory. Merrill, Daniel Alexander Investigation of cellular microenvironments and heterogeneity with biodynamic imaging.

Methel, Cam-Tu Jeanne An experimental comparison of diffuser designs in a centrifugal compressor. Miao, Jinmin Studies in novel transition-metal-catalyzed oxidative coupling reactions. Michuda, Nicolas J Mining big data to create a tool for empirical observation of continuous safety improvement in a construction company - A progressive case study in the lean environment.